Abstract:
This dataset reports chemical analysis of water samples collected during the R/V Endeavor cruise EN586 in the Gulf of Mexico from 2016-07-24 to 2016-08-14, at cold-seep and control sites. Measurements include the concentration of dissolved nutrients, dissolved organics and inorganics, cations, anions and dissolved gases acquired from CTD casts. This dataset also includes methane oxidation and bacterial production rates. The R/V Endeavor cruise EN586 objective was to assess the impacts of the Deepwater Horizon blowout on water chemistry on fallout sites and compare these impacts to naturally occurring oil and gas seeps. The cruise was led by chief scientist Dr. Joseph Montoya. Additional information about this cruise can be found in the R2R repository page: http://www.rvdata.us/catalog/EN586.
Data Parameters and Units:
Location (BOEM lease block), station number, event number, collection type (CTD), latitude and longitude (degrees decimal minutes), date (dd/mm/yy), local time, depth (m), ammonium (NH4, micromol), nitrite (NO2, micromol), nitrate + nitrite (NOx, micromol), nitrate (NO3, micromol), dissolved inorganic nitrogen (DIN, micromol), total dissolved nitrogen (TDN, micromol), dissolved organic nitrogen (DON, micromol), dissolved phosphate (PO4, micromol), total dissolved phosphorus (TDP, micromol), dissolved organic phosphorus (DOP, micromol), dissolved inorganic nitrogen to phosphorus ratio (DIN:DIP, molar ratio), dissolved organic nitrogen to phosphorus ratio (DON:DOP, molar ratio), dissolved organic carbon (DOC, micromol), dissolved inorganic carbon (DIC, mM), dissolved methane (CH4, nM), hydrogen sulfide (H2S, mM), sulfate (mM), chloride (mM), sodium (mM), potassium (mM), magnesium (mM), calcium (mM), methane oxidation (pmol L^-1 d^-1), bacterial production (ng C L^-1 d^-1), N.D. = no data (analysis not performed), B.D.L. = below detection limit, N.S. = no sample, NA = not applicable. DON is not measured directly, it is calculated as DON = TDN-NOx-NH4. The NH4 (in column Q “LAB for DON analysis”) used in the calculation above is from analysis of the frozen samples used for nutrient analyses in the lab and not the in situ value as measured on the ship.
Instruments:
1) NOx, NO2, PO4: Lachat Instruments FIA 8000
2) NH4, TDP, H2S: Hach Spectrophotometer DR2800 and/or Shimadzu Spectrophotometer UV-1601
3) DOC: Shimadzu TOC-V
4) TDN: Shimadzu TOC-V with TNM-1
5) SO4, Cl, Na, K, Mg, Ca: DIONEX ICS-2000
6) DIC: Shimadzu Gas Chromatograph GC-2014 with Methanizer
7) CH4: SRI Gas Chromatograph 8610C
8) NO3, DIN, DON, DOP: Calculation