Abstract:

This paper presents a technique to synthesize amorphous 3.7 ± 1.5 nm cobalt (Co) nanoparticles using dimethyl sulfoxide (DMSO) to function as both the stabilizing agent and the solvent for Co nanoparticles via a quick, solvent-based reduction of Co2+ with NaBH4 in a DMSO solvent. UV–visible spectroscopy analysis was used to determine the minimum amount of reducing agent needed to produce Co nanoparticles so as to limit the waste of reagents. TEM and SEM imaging were used to study the morphology of the Co nanoparticles from the DMSO dispersion and of the Co nanoparticle powder. FT-IR was used to elucidate the nature of the interaction between the Co nanoparticle surface and DMSO. This synthesis method demonstrates that Co nanoparticles can be successfully synthesized by simply using DMSO as a functional solvent, thereby avoiding excessive oxidation and agglomeration in solution.

Suggested Citation:

Roberts, Christopher, Vengsarkar Pranav , and Duggan Jennifer. 2014. Dataset supporting the publication 'The synthesis and arrested oxidation of cobalt nanoparticles using DMSO as a functional solvent'. Distributed by: GRIIDC, Harte Research Institute, Texas A&M University–Corpus Christi. doi:10.7266/N7P848WV

Publications:

Duggan, J. N., Bozack, M. J., & Roberts, C. B. (2013). The synthesis and arrested oxidation of amorphous cobalt nanoparticles using DMSO as a functional solvent. J Nanopart Res, 15(11). doi:10.1007/s11051-013-2089-0

Purpose:

This paper presents a technique to synthesize amorphous 3.7 ± 1.5 nm cobalt (Co) nanoparticles using dimethyl sulfoxide (DMSO) to function as both the stabilizing agent and the solvent for Co nanoparticles via a quick, solvent-based reduction of Co2+ with NaBH4 in a DMSO solvent. This synthesis method demonstrates that Co nanoparticles can be successfully synthesized by simply using DMSO as a functional solvent, thereby avoiding excessive oxidation and agglomeration in solution.

Data Parameters and Units:

Absorbance (no units); Wavenumber (cm-1)

Individual Files: