Abstract:

This dataset reports equilibrium temperature and pressure data for binary (isoxazole + methane) and binary (tetrahydrofuran (THF) + methane) hydrates. Hydrate phase equilibrium conditions were measured through micro-differential scanning calorimetry (MicroDSC VII, Setaram). This work proved isooxazole hydrates can store methane guests in the large cages of sII hydrate structure by way of spectroscopic analyses, such as powder X-ray diffraction and Raman spectroscopy when the methane-isooxazole binary hydrate were formed in different stoichiometry number, C3H3NO∙34H2O. The referred tuning phenomena can occur on methane inclusion in the isooxazole hydrate.

Suggested Citation:

Cha, Minjun, et al. 2015. Dataset for: Tuning Behaviors of Methane Inclusion in Isoxazole Clathrate Hydrates. Distributed by: GRIIDC, Harte Research Institute, Texas A&M University–Corpus Christi. doi:10.7266/N7R78C5G

Publications:

Cha, M., Baek, S., Lee, W., Shin, K., & Lee, J. W. (2015). Tuning Behaviors of Methane Inclusion in Isoxazole Clathrate Hydrates. J. Chem. Eng. Data, 60(2), 278–283. doi:10.1021/je500568f

Purpose:

The goal of this study was to identify tuning behavior of isoxazole clathrate hydrates and to determine equilibrium conditions through the inclusion of methane gas.

Data Parameters and Units:

File Figure 7 and table 2. Equilibrium pressure temperature conditions Temperature (K) = Equilibrium temperature of isoxazole+CH4 hydrate and THF+CH4 hydrate in degree kelvin Pressure (MPa) = Equilibrium pressure of isoxazole+CH4 hydrate and THF+CH4 hydrate in megapascal

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